Collaborative determination of trace element mass fractions and isotope ratios in AQUA-1 drinking water certified reference material

Anal Bioanal Chem. 2021 Aug;413(20):4959-4978. doi: 10.1007/s00216-021-03456-8. Epub 2021 Aug 28.

Abstract

The Isotrace CNRS workgroup in collaboration with National Research Council of Canada has characterized a number of trace element mass fractions and isotope ratios currently not certified in AQUA-1 natural drinking water reference material (NRC Canada). This survey further expands the use of this material as a tool for environmental quality control, method validation, and method development tool for the international community. Simultaneously, the SLRS-6 river water was analyzed as quality control and also in order to compare both water characteristics, which were sampled in the same area but having undergone different treatment. Mass fractions for B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Zr, REEs, and six isotopic ratios are proposed for Sr and Pb. Measurements were mostly performed using ICP-MS with various calibration approaches. The results are reported as consensus or indicative values depending on the number of available datasets, with their associated uncertainties.

Keywords: CRM; Drinking water reference material; Elemental analysis; Isotopic ratios; Rare earth elements; Trace elements.

MeSH terms

  • Drinking Water / chemistry*
  • Reference Standards
  • Trace Elements / chemistry*
  • Water / chemistry*

Substances

  • Drinking Water
  • Trace Elements
  • Water