Technological Aspects of Chemoenzymatic Epoxidation of Fatty Acids, Fatty Acid Esters and Vegetable Oils: A Review

Molecules. 2015 Dec 2;20(12):21481-93. doi: 10.3390/molecules201219778.

Abstract

The general subject of the review is analysis of the effect of technological parameters on the chemoenzymatic epoxidation processes of vegetable oils, fatty acids and alkyl esters of fatty acids. The technological parameters considered include temperature, concentration, amount of hydrogen peroxide relative to the number of unsaturated bonds, the amounts of enzyme catalysts, presence of solvent and amount of free fatty acids. Also chemical reactions accompanying the technological processes are discussed together with different technological options and significance of the products obtained.

Keywords: alkyl fatty acid esters; epoxidation; fatty acids; free fatty acids.

Publication types

  • Review

MeSH terms

  • Catalysis
  • Enzymes, Immobilized*
  • Epoxy Compounds / chemical synthesis*
  • Esters / chemistry*
  • Fatty Acids / chemistry*
  • Plant Oils / chemistry*

Substances

  • Enzymes, Immobilized
  • Epoxy Compounds
  • Esters
  • Fatty Acids
  • Plant Oils