Simultaneous determination of delta33S(V-CDT) and delta34S(V-CDT) using masses 48, 49 and 50 on a continuous flow isotope ratio mass spectrometer

A new, fast, continuous flow technique is described for the simultaneous determination of delta33S and delta34S using SO masses 48, 49 and 50. Analysis time is approximately 5 min/sample with measurement precision and accuracy better than +/-0.3 per thousand. This technique, which has been set up using IAEA Ag2S standards S-1, S-2 and S-3, allows for the fast determination of mass-dependent or mass-independent fractionation (MIF) effects in sulfide, organic sulfur samples and possibly sulfate. Small sample sizes can be analysed directly, without chemical pre-treatment. Robustness of the technique for natural versus artificial standards was demonstrated by analysis of a Canon Diablo troilite, which gave a delta33S of 0.04 per thousand and a delta34S of -0.06 per thousand compared to the values obtained for S-1 of 0.07 per thousand and -0.20 per thousand, respectively. Two pyrite samples from a banded-iron formation from the 3710 Ma Isua Greenstone Belt were analysed using this technique and yielded MIF (Delta33S of 2.45 and 3.31 per thousand) comparable to pyrite previously analysed by secondary ion probe.