trans-Bis[8-(benzyl-sulfan-yl)quinoline-κ2 N, S]di-chlorido-cobalt(II)

Shintaro Kodama; Kazuki Bunno; Akihiro Nomoto; Akiya Ogawa

doi:10.1107/S2414314621009925

trans-Bis[8-(benzyl-sulfan-yl)quinoline-κ² N, S]di-chlorido-cobalt(II)

IUCrdata. 2021 Oct 4;6(Pt 10):x210992. doi: 10.1107/S2414314621009925. eCollection 2021 Oct.

Authors

Shintaro Kodama¹, Kazuki Bunno¹, Akihiro Nomoto¹, Akiya Ogawa¹

Affiliation

¹ Department of Applied Chemistry, Graduate School of Engineering, Osaka, Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan.

Abstract

The title di-chloro-cobalt(II) complex, trans-[CoCl₂(1)₂] [1 = 8-(benzyl-sulfanyl)-quinoline, C₁₆H₁₃NS], has a central Co^II atom (site symmetry ) that exhibits a distorted octa-hedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak inter-molecular C-H⋯π inter-actions between the 8-(benzyl-sulfanyl)-quinoline ligands, forming a chain extending along the a-axis direction.

Keywords: bidentate N,S-ligand; cobalt(II) complex; crystal structure.

Grants and funding

Funding for this research was provided by: Japan Society for the Promotion of Science (grant No. 21H01977; grant No. 19H02791; grant No. 19H02756); Iketani Science and Technology Foundation (grant No. 0331022-A).