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Page 1
The wet oxidation of aqueous humic acids.
García M, Collado S, Oulego P, Díaz M. García M, et al. J Hazard Mater. 2020 Sep 5;396:122402. doi: 10.1016/j.jhazmat.2020.122402. Epub 2020 Feb 24. J Hazard Mater. 2020. PMID: 32298859
Nevertheless, humic acid wet oxidation was not sensitive to changes in the pressure, at least in the range tested (65-95 bar), but the initial pH (4-13) was found to be a key factor. Thus, alkaline media accelerated the humic acid removal, but more refractory intermediates …
Nevertheless, humic acid wet oxidation was not sensitive to changes in the pressure, at least in the range tested (65-95 bar), but th …
Organometallic complexes with terminal imidazolato ligands and their use as metalloligands.
Gómez E, Huertos MA, Pérez J, Riera L, Menéndez-Velázquez A. Gómez E, et al. Inorg Chem. 2010 Oct 18;49(20):9527-34. doi: 10.1021/ic1012395. Inorg Chem. 2010. PMID: 20849127
Compounds [Re(bipy)(CO)(3)(HIm)]OTf (1) and [Mo(eta(3)-C(3)H(4)-R-2)(CO)(2)(HIm)(phen)]BAr'(4) [R = Me (2a), H (2b); Ar' = 3,5-bis(trifluoromethyl)phenyl; HIm = 1H-imidazole] were prepared from 1H-imidazole and either [Re(OTf)(bipy)(CO)(3)] or [MoCl(eta(3)-C(3)H(4)-R-2)(CO …
Compounds [Re(bipy)(CO)(3)(HIm)]OTf (1) and [Mo(eta(3)-C(3)H(4)-R-2)(CO)(2)(HIm)(phen)]BAr'(4) [R = Me (2a), H (2b); Ar' = 3,5-bis(tr …
CO2 Hydrogenation at Atmospheric Pressure and Low Temperature Using Plasma-Enhanced Catalysis over Supported Cobalt Oxide Catalysts.
Ronda-Lloret M, Wang Y, Oulego P, Rothenberg G, Tu X, Shiju NR. Ronda-Lloret M, et al. ACS Sustain Chem Eng. 2020 Nov 30;8(47):17397-17407. doi: 10.1021/acssuschemeng.0c05565. Epub 2020 Nov 17. ACS Sustain Chem Eng. 2020. PMID: 33282570 Free PMC article.
In conventional reactors, because of thermodynamic constraints, converting CO(2) to methanol requires high temperature and pressure, typically 250 C and 20 bar. Nonthermal plasma is a better option, as it can convert CO(2) at near-ambient temperature and pressure. ...
In conventional reactors, because of thermodynamic constraints, converting CO(2) to methanol requires high temperature and pressure, typical …
Rhenium-catalysed hydroboration of aldehydes and aldimines.
Arévalo R, Vogels CM, MacNeil GA, Riera L, Pérez J, Westcott SA. Arévalo R, et al. Dalton Trans. 2017 Jun 28;46(24):7750-7757. doi: 10.1039/c7dt01549f. Epub 2017 Jun 7. Dalton Trans. 2017. PMID: 28589994
A wide array of rhenium complexes were efficient pre-catalysts for these hydroborations, including new low-valent complexes of the formula [Re(N-N)(CO)(3)(L)]X (N-N = bipy derivative, L = labile ligand/solvent, and X = [BAr(F)(4)](-) and [B(3,5- …
A wide array of rhenium complexes were efficient pre-catalysts for these hydroborations, including new low-valent complexes of the formula [ …
Effect of wet oxidation on the fingerprints of polymeric substances from an activated sludge.
Urrea JL, Collado S, Oulego P, Díaz M. Urrea JL, et al. Water Res. 2016 Nov 15;105:282-290. doi: 10.1016/j.watres.2016.09.004. Epub 2016 Sep 7. Water Res. 2016. PMID: 27636151
For a better understanding of these transformations, the sludge was separated into its main fractions: soluble microbial products (SMP), loosely bound extracellular polymeric substances (LB-EPS), tightly bound extracellular polymeric substances (TB-EPS) and naked cells, and then …
For a better understanding of these transformations, the sludge was separated into its main fractions: soluble microbial products (SMP), loo …
Sludge hydrothermal treatments. Oxidising atmosphere effects on biopolymers and physical properties.
Urrea JL, García M, Collado S, Oulego P, Díaz M. Urrea JL, et al. J Environ Manage. 2018 Jan 15;206:284-290. doi: 10.1016/j.jenvman.2017.10.043. Epub 2017 Oct 27. J Environ Manage. 2018. PMID: 29096142
In this work, the role of an oxidising atmosphere during the hydrothermal treatment of an activated sludge at 160 C and 40 bar, was determined. The composition and molecular weight sizes of the soluble biopolymers generated during the sludge treatment in presence (wet oxid …
In this work, the role of an oxidising atmosphere during the hydrothermal treatment of an activated sludge at 160 C and 40 bar, was d …
σ-Silane Platinum(II) Complexes as Intermediates in C-Si Bond-Coupling Processes.
Ríos P, Fouilloux H, Díez J, Vidossich P, Lledós A, Conejero S. Ríos P, et al. Chemistry. 2019 Aug 27;25(48):11346-11355. doi: 10.1002/chem.201902226. Epub 2019 Aug 5. Chemistry. 2019. PMID: 31246316
Platinum complexes [Pt(NHC')(NHC)][BAr(F) ] (in which NHC' denotes a cyclometalated N-heterocyclic carbene ligand, NHC) react with primary silanes RSiH(3) to afford the cyclometalated platinum(II) silyl complexes [Pt(NHC-SiHR')(NHC)][BAr(F) ] through a proces …
Platinum complexes [Pt(NHC')(NHC)][BAr(F) ] (in which NHC' denotes a cyclometalated N-heterocyclic carbene ligand, NHC) react …
Two different hydrogen bond donor ligands together: a selectivity improvement in organometallic {Re(CO)3} anion hosts.
Ion L, Nieto S, Pérez J, Riera L, Riera V, Díaz J, López R, Anderson KM, Steed JW. Ion L, et al. Inorg Chem. 2011 Sep 5;50(17):8524-31. doi: 10.1021/ic201120s. Epub 2011 Aug 11. Inorg Chem. 2011. PMID: 21834508
Rhenium(I) compounds [Re(CO)(3)(Hdmpz)(2)(ampy)]BAr'(4) and [Re(CO)(3)(N-MeIm)(2)(ampy)]BAr'(4) (Hdmpz = 3,5-dimethylpyrazole, N-MeIm = N-methylimidazole, ampy = 2-aminopyridine or 3-aminopyridine) have been prepared stepwise as the sole reactio …
Rhenium(I) compounds [Re(CO)(3)(Hdmpz)(2)(ampy)]BAr'(4) and [Re(CO)(3)(N-MeIm)(2)(ampy)]BAr'(4) (Hdmpz = 3,5-dimethylpy …