Thermal Modeling of the Port on a Refining Furnace to Prevent Copper Infiltration and Slag Accretion

Materials (Basel). 2021 Nov 18;14(22):6978. doi: 10.3390/ma14226978.

Abstract

Fire refining of blister copper is a singular process at very high temperatures (~1400 K), which means the furnace is exposed to heavy thermal loads. The charge is directly heated by an internal burner. The impurities in the charge oxidize with the flux of hot gases, creating a slag layer on the top of the molten bath. This slag is periodically removed, which implies liquid metal flowing through the furnace port. To address its malfunction, a re-design of the furnace port is presented in this work. Due to the lack of previous technical information, the convective heat transfer coefficient between the slag and the furnace port was characterized through a combination of an experimental test and a three-dimensional transient model. Finally, the original design of the furnace port was analyzed and modifications were proposed, resulting in a reduction of the average temperature of the critical areas up to 300 K. This improvement prevents the anchoring of the accretion layer over the port plates and the steel plate from being attacked by the copper.

Keywords: copper infiltration; high-temperature heat transfer; model fitting; refining furnace; thermal modeling.