A series of poly(ethylene oxide)-LiOTf electrolyte films were prepared using a variety of hydrocarbon templates as nanofillers, resulting in observable nanophase separation in the polymer electrolyte. Upon partial extraction of the nanofiller template, an enhanced conductivity over 2 orders of magnitude was measured using ac impedance. Scanning electron microscopy, differential scanning calorimetry, and thermogravimetric analysis were employed to characterize the porosity, composition, and mass loss of template-extracted and nonextracted film samples.
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