Microstructure and Mechanical Properties of Galvanized-45 Steel/AZ91D Bimetallic Material by Liquid-Solid Compound Casting

Materials (Basel). 2019 May 21;12(10):1651. doi: 10.3390/ma12101651.

Abstract

A connection between hot-dip galvanized 45 steel and AZ91D was achieved by liquid-solid compound casting to achieve one material with a better mechanical performance and a light weight. The microstructure and properties of galvanized-steel/AZ91D bimetallic materials were investigated in this study. A scanning electron microscopy (SEM), an energy dispersive spectroscopy (EDS), and an X-ray diffraction (XRD) were applied to analyze the microstructure evolution and formation mechanism of the galvanized 45 steel/AZ91D interface zone which could be divided into three layers. Among three different layers, the layer close to AZ91D was composed of α-Mg and an eutectic structure (α-Mg + MgZn). The intermediate layer was comprised of an eutectic structure (α-Mg + MgZn), and the layer adjacent to 45 steel consisted of α-Mg and FeAl3. Furthermore, galvanized-45 steel/AZ91D bimetallic material had better shear strength than the bare-45 steel/AZ91D metallic material which can indicate that owing to the formation of metallurgical bonding, the adhesive strength of galvanized-steel and AZ91D was improved to 11.81 MPa. In addition, the fact that corrosion potential increased from -1.493 V to -1.143 V and corrosion current density changed from 3.015 × 10-5 A/cm2 to 1.34 × 10-7 A/cm2 implied that the corrosion resistance of galvanized-steel/AZ91D was much better than AZ91D.

Keywords: hot-dip galvanizing; interface microstructure; intermediate compound; solid-liquid compound casting.