Investigation of BiVO₄-based advanced oxidation system for decomposition of organic compounds and production of reactive sulfate species

Growth of population and expansion of industries lead to increasing contamination of environment with various organic pollutants. If not properly cleaned, wastewater contaminates freshwater resources, aquatic environment and has huge negative impact on ecosystems, quality of drinking water and human health, therefore new and effective purification systems are in demand. In this work bismuth vanadate-based advanced oxidation system (AOS) for the decomposition of organic compounds and production of reactive sulfate species (RSS) was investigated. Pure and Mo-doped BiVO₄ coatings were synthesized using sol-gel process. Composition and morphology of coatings were characterized using X-ray diffraction and scanning electron microscopy techniques. Optical properties were analyzed using UV-vis spectrometry. Photoelectrochemical performance was studied using linear sweep voltammetry, chronoamperometry and electrochemical impedance spectroscopy. It was shown that increase in Mo content affects the morphology of BiVO₄ films, reduces charge transfer resistance and enhances the photocurrent in the solutions of sodium borate buffer (with and without glucose) and Na₂SO₄. Mo-doping of 5-10 at.% leads to 2- to 3-fold increase in photocurrents. Faradaic efficiencies of RSS formation ranged between 70 and 90 % for all samples irrespective of Mo content. All studied coatings demonstrated high stability in long-lasting photoelectrolysis. In addition, effective light-assisted bactericidal performance of the films in deactivation of Gram positive Bacillus sp. bacteria was demonstrated. Advanced oxidation system designed in this work can be applied in sustainable and environmentally friendly water purification systems.