Assessment of Technological Capabilities for Forming Al-C-B System Coatings on Steel Surfaces by Electrospark Alloying Method

Bogdan Antoszewski; Oksana P Gaponova; Viacheslav B Tarelnyk; Oleksandr M Myslyvchenko; Piotr Kurp; Tetyana I Zhylenko; Ievgen Konoplianchenko

doi:10.3390/ma14040739

Assessment of Technological Capabilities for Forming Al-C-B System Coatings on Steel Surfaces by Electrospark Alloying Method

Materials (Basel). 2021 Feb 5;14(4):739. doi: 10.3390/ma14040739.

Authors

Bogdan Antoszewski¹, Oksana P Gaponova², Viacheslav B Tarelnyk³, Oleksandr M Myslyvchenko⁴, Piotr Kurp¹, Tetyana I Zhylenko², Ievgen Konoplianchenko³

Affiliations

¹ Laser Research Centre, Faculty of Mechatronics and Mechanical Engineering, Kielce University of Technology, Al. Tysiąclecia P.P. 7, 25-314 Kielce, Poland.
² The Department of Applied Material Science and Technology of Constructional Materials, Sumy State University, R. Korsakov Str., 2, 40007 Sumy, Ukraine.
³ Technical Services Department, Sumy National Agrarian University, H. Kondratiieva Str., 160, 40021 Sumy, Ukraine.
⁴ Department of Physical Chemistry of Inorganic Materials, Frantsevich Institute for Problems of Materials Science, Krzhizhanovsky Str. 3, 03142 Kyiv, Ukraine.

Abstract

In this paper, the possibility of applying the electrospark alloying (ESA) method to obtain boron-containing coatings characterised by increased hardness and wear resistance is considered. A new method for producing such coatings is proposed. The method consists in applying grease containing aluminium powder and amorphous boron to the surface to be treated and subsequently processing the obtained surface using the ESA method by a graphite electrode. The microstructural analysis of the Al-C-B coatings on steel C40 showed that the surface layer consists of several zones, the number and parameters of which are determined by the energy conditions of the ESA process. Durametric studies showed that with an increase in the discharge energy influence, the microhardness values of both the upper strengthened layer and the diffusion zone increased to W_p = 0.13 J, Hµ = 6487 MPa, and W_p = 4.9 J, Hµ = 12350 MPa, respectively. The results of X-ray diffraction analysis indicate that at the discharge energies of 0.13 and 0.55 J, the phase composition of the coating is represented by solid solutions of body-centred cubic lattice (BCC) and face-centred cubic lattice (FCC). The coatings obtained at W_p = 4.9 J were characterised by the presence of intermetallics Fe₄Al₁₃ and borocementite Fe₃ (CB) in addition to the solid solutions. The X-ray spectral analysis of the obtained coatings indicated that during the electrospark alloying process, the surface layers were saturated with aluminium, boron, and carbon. With increasing discharge energy, the diffusion zone increases; during the ESA process with the use of the discharge energy of 0.13 J for steel C40, the diffusion zone is 10-15 μm. When replacing a substrate made of steel C40 with the same one material but of steel C22, an increase in the thickness of the surface layer accompanied by a slight decrease in microhardness is observed as a result of processing with the use of the ESA method. There were simulated phase portraits of the Al-C-B coatings. It is shown that near the stationary points in the phase portraits, one can see either a slowing down of the evolution or a spiral twisting of the diffusion-process particle.

Keywords: X-ray diffraction analysis; X-ray spectral analysis; coatings; continuity; electrospark alloying; microhardness; roughness; structure.