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A perimidine-derived non-Kekulé triplet diradical.
Quast H, Nüdling W, Klemm G, Kirschfeld A, Neuhaus P, Sander W, Hrovat DA, Borden WT. Quast H, et al. J Org Chem. 2008 Jul 4;73(13):4956-61. doi: 10.1021/jo800589y. Epub 2008 Jun 12. J Org Chem. 2008. PMID: 18547111
Experimental and theoretical study of stabilization of delocalized forms of semibullvalenes and barbaralanes by dipolar and polarizable solvents. Observation of a delocalized structure that is lower in free energy than the localized form.
Seefelder M, Heubes M, Quast H, Edwards WD, Armantrout JR, Williams RV, Cramer CJ, Goren AC, Hrovat DA, Borden WT. Seefelder M, et al. Among authors: quast h. J Org Chem. 2005 Apr 29;70(9):3437-49. doi: 10.1021/jo0502089. J Org Chem. 2005. PMID: 15844976