Integrating major agricultural practices into the TRIPLEX-GHG model v2.0 for simulating global cropland nitrous oxide emissions: Development, sensitivity analysis and site evaluation

Nitrous oxide (N₂O) emissions from croplands are one of the most important greenhouse gas sources while the estimation of which remains large uncertainties globally. To simulate N₂O emissions from global croplands, the process-based TRIPLEX-GHG model v2.0 was improved by coupling the major agricultural activities. Sensitivity experiment was used to measure the impact of the integrated processes to modeled N₂O emission found chemical N fertilization have the highest relative effect sizes. While the coefficient of the NO₃^- consumption rate for denitrification (COE_dNO3), controlling the first step of the denitrification process was identified to be the most sensitive parameter based on sensitivity analysis of model parameters. The model performed well when simulating the magnitude of the daily N₂O emissions for 39 calibration sites and the continental mean of the parameters were used to producing reasonable estimations for the means of the measured daily N₂O fluxes (R² = 0.87, slope = 1.07) and emission factors (EFs, R² = 0.70, slope = 0.72) during the experiment periods. The model reliability was further confirmed by model validation. General trend of modeled daily N₂O emissions were reasonably consistent with the observations of selected validated sites. In addition, high correlations between the results of modeled and observed mean N₂O emissions (R² = 0.86, slope = 0.82) and EFs (R² = 0.66, slope = 0.83) from 68 validation sites were obtained. Further improvement on more detailed estimations for the variation of the environmental factors, management effects as well as accurate model input model driving data are required to reduce the uncertainties of model simulations. Consequently, our simulation results demonstrate that the TRIPLEX-GHG model v2.0 can reliably estimate N₂O emissions from various croplands at the global scale, which contributes to closing global N₂O budget and sustainable development of agriculture.