Polyvinylidene difluoride (PVDF) mixed matrix membranes loaded with inorganic TiO₂ nanoparticles have received increasing attention in the last few years as self-cleaning membranes for possible application in wastewater treatment and seawater filtration. These novel membranes show increased hydrophilicity, stability and catalytic activity under UV-A irradiation. In this work, PVDF-TiO₂ hollow fibers were prepared by employing new strategies for enhancing the stability of the TiO₂ dispersion, reducing particle agglomeration and improving their distribution. The spinning conditions for producing ultrafiltration hollow fiber membranes from PVDF material and nano-TiO₂ were investigated. Finally, the optimized fibers have been characterized and tested for methylene blue (MB) degradation in water and salty seawater, revealing good permeability, long-term stability under UV-A irradiation, and photo-catalytic activity in both test solutions.
Keywords: PVDF; TiO2; hollow fiber membranes; mixed matrix membrane; photocatalytic degradation; ultrafiltration.