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A free-radical design featuring an intramolecular migration for a synthetically versatile alkyl-(hetero)arylation of simple olefins.
Chem Sci. 2024 Feb 2;15(11):4031-4040. doi: 10.1039/d3sc06476j. eCollection 2024 Mar 13.
Chem Sci. 2024.
PMID: 38487219
Free PMC article.
An Electrochemical Design for Catalytic Dehydration: Direct, Room-Temperature Esterification without Acid or Base Additives.
Han J, Haines CA, Piane JJ, Filien LL, Nacsa ED.
Han J, et al. Among authors: nacsa ed.
J Am Chem Soc. 2023 Jul 26;145(29):15680-15687. doi: 10.1021/jacs.3c04732. Epub 2023 Jul 12.
J Am Chem Soc. 2023.
PMID: 37436909
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Higher-Order Cyclopropenimine Superbases: Direct Neutral Brønsted Base Catalyzed Michael Reactions with α-Aryl Esters.
Nacsa ED, Lambert TH.
Nacsa ED, et al.
J Am Chem Soc. 2015 Aug 19;137(32):10246-53. doi: 10.1021/jacs.5b05033. Epub 2015 Aug 4.
J Am Chem Soc. 2015.
PMID: 26131761
Free PMC article.
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Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols.
Nacsa ED, MacMillan DWC.
Nacsa ED, et al.
J Am Chem Soc. 2018 Mar 7;140(9):3322-3330. doi: 10.1021/jacs.7b12768. Epub 2018 Feb 22.
J Am Chem Soc. 2018.
PMID: 29400958
Free PMC article.
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The development of catalytic nucleophilic substitution reactions: challenges, progress and future directions.
An J, Denton RM, Lambert TH, Nacsa ED.
An J, et al. Among authors: nacsa ed.
Org Biomol Chem. 2014 May 21;12(19):2993-3003. doi: 10.1039/c4ob00032c.
Org Biomol Chem. 2014.
PMID: 24699913
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Cyclopropenone catalyzed substitution of alcohols with mesylate ion.
Nacsa ED, Lambert TH.
Nacsa ED, et al.
Org Lett. 2013 Jan 4;15(1):38-41. doi: 10.1021/ol302970c. Epub 2012 Dec 13.
Org Lett. 2013.
PMID: 23237617
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