Anisotropic Metal-Metal Pauli Repulsion in Polynuclear d10 Metal Clusters.
Xu S, Wan Q, Yang J, Che CM.
Xu S, et al. Among authors: wan q.
J Phys Chem Lett. 2024 Feb 29;15(8):2193-2201. doi: 10.1021/acs.jpclett.3c03434. Epub 2024 Feb 19.
J Phys Chem Lett. 2024.
PMID: 38373151
Metallophilicity has been widely considered to be the driving force for self-assembly of closed-shell d(10) metal complexes, but this view has been challenged by recent studies showing that metallophilicity in linear d(10)-d(10) dimers is repulsive. This is due to strong metal-me …
Metallophilicity has been widely considered to be the driving force for self-assembly of closed-shell d(10) metal complexes, but this view h …