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A New Type of Valence Tautomerism in Cobalt Dioxolene Complexes - Temperature-Induced Transition from a Cobalt(III) Catecholate to a Low-Spin Cobalt(II) Semiquinonate State.
Chemistry. 2023 May 26;29(30):e202300091. doi: 10.1002/chem.202300091. Epub 2023 Apr 17.
Chemistry. 2023.
PMID: 36808779
A bis-NHC-CAAC dimer derived dicationic diradical.
Nayak MK, Sarkar P, Elvers BJ, Mehta S, Zhang F, Chrysochos N, Krummenacher I, Vijayakanth T, Narayanan RS, Dolai R, Roy B, Malik V, Rawat H, Mondal A, Boomishankar R, Pati SK, Braunschweig H, Schulzke C, Ravat P, Jana A.
Nayak MK, et al. Among authors: dolai r.
Chem Sci. 2022 Sep 21;13(42):12533-12539. doi: 10.1039/d2sc03937k. eCollection 2022 Nov 2.
Chem Sci. 2022.
PMID: 36382295
Free PMC article.
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Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC versus CAAC as Donor Substituents.
Dolai R, Kumar R, Elvers BJ, Pal PK, Joseph B, Sikari R, Nayak MK, Maiti A, Singh T, Chrysochos N, Jayaraman A, Krummenacher I, Mondal J, Priyakumar UD, Braunschweig H, Yildiz CB, Schulzke C, Jana A.
Dolai R, et al.
Chemistry. 2023 Jan 9;29(2):e202202888. doi: 10.1002/chem.202202888. Epub 2022 Nov 15.
Chemistry. 2023.
PMID: 36129127
Free PMC article.
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Synthesis and reactivity of NHC-coordinated phosphinidene oxide.
Dhara D, Pal PK, Dolai R, Chrysochos N, Rawat H, Elvers BJ, Krummenacher I, Braunschweig H, Schulzke C, Chandrasekhar V, Priyakumar UD, Jana A.
Dhara D, et al. Among authors: dolai r.
Chem Commun (Camb). 2021 Sep 21;57(75):9546-9549. doi: 10.1039/d1cc04421d.
Chem Commun (Camb). 2021.
PMID: 34546278
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Influence of N-Substitution on the Formation and Oxidation of NHC-CAAC-Derived Triazaalkenes.
Mandal D, Dolai R, Kumar R, Suhr S, Chrysochos N, Kalita P, Narayanan RS, Rajaraman G, Schulzke C, Sarkar B, Chandrasekhar V, Jana A.
Mandal D, et al. Among authors: dolai r.
J Org Chem. 2019 Jul 19;84(14):8899-8909. doi: 10.1021/acs.joc.9b00774. Epub 2019 Jun 27.
J Org Chem. 2019.
PMID: 31187990
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Direct access to 2-aryl substituted pyrrolinium salts for carbon centre based radicals without pyrrolidine-2-ylidene alias cyclic(alkyl)(amino)carbene (CAAC) as a precursor.
Mandal D, Sobottka S, Dolai R, Maiti A, Dhara D, Kalita P, Narayanan RS, Chandrasekhar V, Sarkar B, Jana A.
Mandal D, et al. Among authors: dolai r.
Chem Sci. 2019 Feb 28;10(14):4077-4081. doi: 10.1039/c8sc05477k. eCollection 2019 Apr 14.
Chem Sci. 2019.
PMID: 31049189
Free PMC article.
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"Abnormal" Addition of NHC to a Conjugate Acid of CAAC: Formation of N-Alkyl-Substituted CAAC.
Mandal D, Dolai R, Kalita P, Narayanan RS, Kumar R, Sobottka S, Sarkar B, Rajaraman G, Chandrasekhar V, Jana A.
Mandal D, et al. Among authors: dolai r.
Chemistry. 2018 Aug 27;24(48):12722-12727. doi: 10.1002/chem.201802587. Epub 2018 Jul 23.
Chemistry. 2018.
PMID: 29797625
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Stepwise Reversible Oxidation of N-Peralkyl-Substituted NHC-CAAC Derived Triazaalkenes: Isolation of Radical Cations and Dications.
Mandal D, Dolai R, Chrysochos N, Kalita P, Kumar R, Dhara D, Maiti A, Narayanan RS, Rajaraman G, Schulzke C, Chandrasekhar V, Jana A.
Mandal D, et al. Among authors: dolai r.
Org Lett. 2017 Oct 20;19(20):5605-5608. doi: 10.1021/acs.orglett.7b02721. Epub 2017 Oct 2.
Org Lett. 2017.
PMID: 28968127
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