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Revisiting the assignment of innocent and non-innocent counterions in lanthanide(III) solution chemistry.
Dalton Trans. 2022 May 24;51(20):7936-7949. doi: 10.1039/d2dt00565d.
Dalton Trans. 2022.
PMID: 35543234
We are never ever getting (back to) ideal symmetry: structure and luminescence in a ten-coordinated europium(III) sulfate crystal.
Storm Thomsen M, Anker AS, Kacenauskaite L, Sørensen TJ.
Storm Thomsen M, et al.
Dalton Trans. 2022 Jun 13;51(23):8960-8963. doi: 10.1039/d2dt01522f.
Dalton Trans. 2022.
PMID: 35660819
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Delicate, a study of the structural changes in ten-coordinated La(III), Ce(III), Pr(III), Nd(III), Sm(III) and Eu(III) sulfates.
Storm Thomsen M, Sørensen TJ.
Storm Thomsen M, et al.
Dalton Trans. 2022 Jun 13;51(23):8964-8974. doi: 10.1039/d2dt00832g.
Dalton Trans. 2022.
PMID: 35670220
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Long story short: donor set symmetry in [Eu(DOTA)(H2O)]- crystals determines the electronic structure.
Storm Thomsen M, Andersen HOB, Sørensen TJ.
Storm Thomsen M, et al.
Dalton Trans. 2022 Sep 26;51(37):14118-14124. doi: 10.1039/d2dt02172b.
Dalton Trans. 2022.
PMID: 36043508
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Invisible strings. The first single crystal of the cTSAP form of [Eu(DOTA)(H2O)]- has an electronic structure similar to one of the reported cSAP forms.
Storm Thomsen M, Parsons S, Sørensen TJ.
Storm Thomsen M, et al.
Dalton Trans. 2022 Oct 25;51(41):15725-15733. doi: 10.1039/d2dt02633c.
Dalton Trans. 2022.
PMID: 36178013
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