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The electron-poor phosphines P{C6H3(CF3)2-3,5}3 and P(C6F5)3 do not mimic phosphites as ligands for hydroformylation. A comparison of the coordination chemistry of P{C6H3(CF3)2-3,5}3 and P(C6F5)3 and the unexpectedly low hydroformylation activity of their rhodium complexes.
Clarke ML, Ellis D, Mason KL, Orpen AG, Pringle PG, Wingad RL, Zaher DA, Baker RT. Clarke ML, et al. Among authors: pringle pg. Dalton Trans. 2005 Apr 7;(7):1294-300. doi: 10.1039/b418193j. Epub 2005 Feb 28. Dalton Trans. 2005. PMID: 15782267
Stable fluorophosphines: predicted and realized ligands for catalysis.
Fey N, Garland M, Hopewell JP, McMullin CL, Mastroianni S, Orpen AG, Pringle PG. Fey N, et al. Among authors: pringle pg. Angew Chem Int Ed Engl. 2012 Jan 2;51(1):118-22. doi: 10.1002/anie.201105954. Epub 2011 Nov 11. Angew Chem Int Ed Engl. 2012. PMID: 22076744 No abstract available.
47 results