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Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung.
Chem Commun (Camb). 2014 Sep 11;50(70):10008-18. doi: 10.1039/c4cc03198a.
Chem Commun (Camb). 2014.
PMID: 24911768
Review.
Copper-catalyzed oxidative alkynylation of diaryl imines with terminal alkynes: a facile synthesis of ynimines.
Laouiti A, Rammah MM, Rammah MB, Marrot J, Couty F, Evano G.
Laouiti A, et al.
Org Lett. 2012 Jan 6;14(1):6-9. doi: 10.1021/ol2032152. Epub 2011 Dec 15.
Org Lett. 2012.
PMID: 22171540
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Exploring the anionic reactivity of ynimines, useful precursors of metalated ketenimines.
Laouiti A, Couty F, Marrot J, Boubaker T, Rammah MM, Rammah MB, Evano G.
Laouiti A, et al.
Org Lett. 2014 Apr 18;16(8):2252-5. doi: 10.1021/ol500749h. Epub 2014 Apr 4.
Org Lett. 2014.
PMID: 24702158
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