Photosensitized oxidation of alkyl phenyl sulfoxides. C-S bond cleavage in alkyl phenyl sulfoxide radical cations.
Baciocchi E, Del Giacco T, Lanzalunga O, Mencarelli P, Procacci B.
Baciocchi E, et al. Among authors: del giacco t.
J Org Chem. 2008 Aug 1;73(15):5675-82. doi: 10.1021/jo801088n. Epub 2008 Jun 26.
J Org Chem. 2008.
PMID: 18578497
An estimate of the difference in the C-S bond cleavage rate between sulfoxide and sulfide radical cations was possible by comparing the fragmentation rate of 5(*+) (1.4 x 10(6) s(-1)) with the upper limit (10(4) s(-1)) given for tert-butyl phenyl sulfide radical cation (Baciocchi …
An estimate of the difference in the C-S bond cleavage rate between sulfoxide and sulfide radical cations was possible by comparing the frag …