Abstract
The arene dioxides of five 1-substituted pyrenes have been synthesized using dimethyldioxirane. The diasteroisomeric distribution of the dioxides has been determined. X-ray crystallographic structures of the dioxides have also been obtained. These structures show that for the cis dioxides the molecular structures show a departure from planarity, the extent of which is dependent on the substituent.
Publication types
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Comparative Study
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Research Support, U.S. Gov't, Non-P.H.S.
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Carcinogens / chemical synthesis*
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Carcinogens / chemistry
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Crystallography, X-Ray
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Epoxy Compounds
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Magnetic Resonance Spectroscopy
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Molecular Structure
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Pyrenes / chemical synthesis*
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Pyrenes / chemistry
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Stereoisomerism
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Structure-Activity Relationship
Substances
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Carcinogens
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Epoxy Compounds
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Pyrenes
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dimethyldioxirane