cis-9,cis-15-octadecadienoic acid: a novel fatty acid found in higher plants

Biochim Biophys Acta. 1993 Nov 3;1170(3):245-52. doi: 10.1016/0005-2760(93)90006-u.

Abstract

An unusual fatty acid, cis-9,cis-15-octadecadienoic acid, has been identified in the pulp lipids of mango (Mangifera indica L.) grown in the Philippines. To our knowledge, the occurrence of cis-9,cis-15-octadecadienoic acid in higher plant lipids has not been previously reported. The structure confirmation was based on the results of chromatographic (capillary GC, argentation thin-layer) and spectrometric (GC-MS, infrared, ultraviolet) analysis and chemical treatment. This butylene-interrupted dienoic fatty acid is concentrated in the pulp part of mango fruit and occupies 5.4% of total acyl groups in the pulp lipids; whereas a common octadecadienoic acid, linoleic acid, is a minor component (1.1%) in the same lipids. If a trivial name is desired, it is suggested that cis-9,cis-15-octadecadienoic acid be called "mangiferic" acid.

MeSH terms

  • Chromatography, Gas
  • Fruit / chemistry*
  • Gas Chromatography-Mass Spectrometry
  • Isomerism
  • Linoleic Acids / analysis*
  • Linoleic Acids / chemistry
  • Philippines
  • Spectrophotometry

Substances

  • Linoleic Acids
  • 9,15-octadecadienoic acid