Impact of Carbon-Based Nanoparticles on Polyvinyl Alcohol Polarizer Features: Photonics Applications

Nanomaterials (Basel). 2024 Apr 23;14(9):737. doi: 10.3390/nano14090737.

Abstract

Among different inorganic and organic polarizer elements, thin-film light polarizers occupy a special place because of their flexibility, ease of integration into any optoelectronic circuit, and good functioning in the visible and near-infrared spectral range and can compete with Glan and Nicolas volumetric prisms. This paper presents the results of a study on how carbon-based nanoparticles influence on the basic properties of a well-known PVA-based polymer matrix, using which it is possible to obtain good transparency for parallel light components. An accent is made on graphene oxide nanoparticles, which are used as PVA sensitizers. It was shown for the first time that the structuring of PVA with graphene oxides allows an increased transmittance of the parallel light component to be obtained, saving the transmittance of the orthogonal one. Moreover, the graphene network can increase the mechanical strength of such thin-film PVA-based polarizers and provoke a change in the wetting angle. These advantages make it possible to use graphene oxide-structured thin-film light polarizers based on a PVA matrix as an independent optoelectronic element. Some comparative results for polarizers based on PVA-C70 structures are shown as well.

Keywords: fullerenes; graphene oxide nanoparticles; microhardness; modeling; polyvinyl alcohol thin film; spectral characteristics; wetting (contact) angle.

Grants and funding

This research was carried out at the expense of a grant from the Russian Science Foundation, project No. 24-23-00021, (2024–2025). https://rscf.ru/prjcard_int%20?24-23-00021, accessed on 25 January 2023.