Tetraphenylene-based semiconductive metal-organic framework crystals for direct X-ray detection and imaging

Qi Luo; Yuxia Li; Xin Huang; Yi Zheng; Qi Gu; Shuaihua Wang; Shaofan Wu

doi:10.1039/d4cc01188k

Tetraphenylene-based semiconductive metal-organic framework crystals for direct X-ray detection and imaging

Chem Commun (Camb). 2024 May 21;60(42):5510-5513. doi: 10.1039/d4cc01188k.

Authors

Qi Luo^{1

2}, Yuxia Li^{1

2}, Xin Huang², Yi Zheng², Qi Gu³, Shuaihua Wang^{2

4}, Shaofan Wu^{2

4}

Affiliations

¹ College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, China.
² State Key Laboratory of Structural Chemistry, Fujian Institute of Research on Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. shwang@fjirsm.ac.cn.
³ College of Materials Science and Engineering, Sichuan University, Chengdu 610065, Sichuan, China.
⁴ University of Chinese Academy of Science (UCAS), Beijing 100049, China.

PMID: 38690879
DOI: 10.1039/d4cc01188k

Abstract

MOFs have good potential for X-ray detection, but direct X-ray detection in single crystal form is rarely reported. In this work, we successfully synthesized Pb-TCPE, and the single crystal achieves a low detection limit and high detection sensitivity of 4812.6 μC Gy_air^-1 cm^-2, which exhibits great potential for X-ray detection and imaging.