Effective removal of nitrate and phosphate using graphene nanosheets synthesized from waste plastics

Abstract

In this work, waste plastics have been used with bentonite clay to produce silica-containing graphene nanosheets (GNs) for adsorption of nitrate and phosphate from synthetic water. The GNs were obtained by the two steps process, namely (1) pyrolysis at 750 °C and (2) ball milling. Then, GNs were characterized by Raman spectroscopy, FTIR, XRD, FESEM, HRTEM and EDX spectroscopy, which provided the details of material's morphology, surface properties, and composition. From Raman spectroscopy, D and G bands were found at 1342 cm^-1 and 1594 cm^-1, respectively, which confirmed the presence of nanosheets on the graphene surface. Furthermore, the layers of nanosheets were confirmed by the HRTEM analysis and XRD peaks. In analytical study, the batch experiment was conducted to investigate the influence of operational parameters such as pH (03-12), contact time (05-120 min), adsorbent dosage (0.01-0.06 g), and initial concentrations of adsorbates (10-50 mg/L for nitrate and 03-15 mg/L for phosphate) on adsorption process. The removal percentage of nitrate and phosphate at optimum dosage = 0.05 g, pH = 6.5, contact time = 60 min, nitrate concentration = 30 mg/L, and phosphate concentration = 09 mg/L were found to be 85 and 91, respectively. The highest adsorption capacity of nitrate and phosphate was found to be 53 mg/g and 16.4 mg/g, respectively. The adsorption behaviour of both nitrate and phosphate showed chemisorption as the experimental data were well fitted by the pseudo-2nd-order kinetic and Langmuir isotherm model. Life cycle cost analysis (LCCA) of the synthesis process was conducted to evaluate the cost-benefit analysis for commercial feasibility. The estimated price for the synthesis of GNs using 1 kg of waste plastics and bentonite clay as precursor was $4.21, suggesting commercialization.

Keywords: Adsorption; Graphene nanosheets; Nitrate; Phosphate; Waste plastics.