Tetrabutylammonium decatungstate (TBADT) has recently emerged as an intriguing photocatalyst under visible-light or near-visible-light irradiation in a wide range of organic reactions that were previously not conceivable. Given its ability to absorb visible light and excellent effectiveness in activating unactivated chemical bonds, it is a promising addition to traditional photocatalysts. This review covers some of the contemporary developments in visible-light or near-visible-light photocatalysis reactions enabled by the TBADT catalyst to 2023, with the contents organized by reaction type.