Crystalline metal phosphide-coated amorphous iron oxide-hydroxide (FeOOH) with oxygen vacancies as highly active and stable oxygen evolution catalyst in alkaline seawater at high current density

Wei Yan; Zhuang Shi; Hao Feng; Jinshi Yu; Wenmiao Chen; Yanli Chen

doi:10.1016/j.jcis.2024.04.091

Crystalline metal phosphide-coated amorphous iron oxide-hydroxide (FeOOH) with oxygen vacancies as highly active and stable oxygen evolution catalyst in alkaline seawater at high current density

J Colloid Interface Sci. 2024 Aug:667:362-370. doi: 10.1016/j.jcis.2024.04.091. Epub 2024 Apr 15.

Authors

Wei Yan¹, Zhuang Shi², Hao Feng², Jinshi Yu², Wenmiao Chen³, Yanli Chen⁴

Affiliations

¹ School of Science, Jiangsu Key Laboratory of Function Control Technology for Advanced Materials, Jiangsu Ocean University, Lianyungang, Jiangsu 222005, PR China; School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, PR China.
² School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, PR China.
³ School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, PR China. Electronic address: wmchen@upc.edu.cn.
⁴ School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, PR China. Electronic address: yanlichen@upc.edu.cn.

PMID: 38640655
DOI: 10.1016/j.jcis.2024.04.091

Abstract

In this study, we employed a straightforward phosphorylation approach to achieve a dual objective: constructing c-a heterostructures consisting of crystalline Ni₁₂P₅ and amorphous FeOOH, while simultaneously enhancing oxygen vacancies. The resulting oxygen evolution reaction (OER) catalyst, Ni₁₂P₅/FeOOH/NF, exhibited remarkable performance with current densities of 500 mA cm^-2 in both 1 M KOH and 1 M KOH + seawater, requiring low overpotentials of only 288 and 365 mV, respectively. Furthermore, Ni₁₂P₅/FeOOH/NF exhibited only a slight increase in overpotential, with increments of 18 mV and 70 mV in 1 M KOH after 15 and 150 h, and 32 mV and 108 mV in 1 M KOH + seawater at 500 mA cm^-2 after 15 and 150 h, respectively. This minimal change can be attributed to the stabilized c-a structure, the protective coating of Ni₁₂P₅, and superhydrophilic. Through in-situ Raman and ex-situ XPS analysis, we discovered that Ni₁₂P₅/FeOOH/NF can undergo a reconfiguration into an oxygen vacancy-rich (Fe/Ni)OOH phase during OER process. The elevated OER activity is mainly due to the contribution of the oxygen vacancy-rich (Fe/Ni)OOH phase from the reconfigure of the Ni₁₂P₅/FeOOH/NF. This finding emphasizes the critical role of oxygen vacancies in facilitating the production of OO species and overcoming the limitations associated with OOH formation, ultimately enhancing the kinetics of the OER.

Keywords: Amorphous FeOOH; Heterojunction; OER; Oxygen vacancies; Seawater splitting.