Functionalized Single Crystal Perovskite Materials for SERS and Their Potential Detection Applications

Muhammad Awais; Syed Muhammad Zaigham Abbas Naqvi; Zhang Wei; Junfeng Wu; Ifzan Arshad; Vijaya Raghavan; Sami Ullah Khan; Jiandong Hu

doi:10.1007/s10895-024-03716-7

Functionalized Single Crystal Perovskite Materials for SERS and Their Potential Detection Applications

J Fluoresc. 2024 Apr 13. doi: 10.1007/s10895-024-03716-7. Online ahead of print.

Authors

Muhammad Awais^{1

2

3}, Syed Muhammad Zaigham Abbas Naqvi^{4

5

6}, Zhang Wei^{1

2

3}, Junfeng Wu^{1

2

3}, Ifzan Arshad^{7

8}, Vijaya Raghavan⁹, Sami Ullah Khan¹⁰, Jiandong Hu^{11

12

13}

Affiliations

¹ Department of Mechanical and Electrical Engineering, Henan Agricultural University, Zhengzhou, 450002, China.
² Henan International Joint Laboratory of Laser Technology in Agriculture Sciences, Zhengzhou, 450002, China.
³ State Key Laboratory of Wheat and Maize Crop Science, Zhengzhou, 450002, China.
⁴ Department of Mechanical and Electrical Engineering, Henan Agricultural University, Zhengzhou, 450002, China. zaigham@stu.henau.edu.cn.
⁵ Henan International Joint Laboratory of Laser Technology in Agriculture Sciences, Zhengzhou, 450002, China. zaigham@stu.henau.edu.cn.
⁶ State Key Laboratory of Wheat and Maize Crop Science, Zhengzhou, 450002, China. zaigham@stu.henau.edu.cn.
⁷ Institute for Advanced Study, Shenzhen University, Shenzhen, 518060, Guangdong, China.
⁸ College of Civil and Transportation Engineering, Shenzhen University, Shenzhen, China.
⁹ Department of Bioresource Engineering, Faculty of Agriculture and Environmental Studies, McGill University, Sainte-Anne-de-Bellevue, Quebec, H9X 3V9, Canada.
¹⁰ Department of Mathematics, Namal University, Talagang Road, Mianwali, 42250, Pakistan.
¹¹ Department of Mechanical and Electrical Engineering, Henan Agricultural University, Zhengzhou, 450002, China. jdhu@henau.edu.cn.
¹² Henan International Joint Laboratory of Laser Technology in Agriculture Sciences, Zhengzhou, 450002, China. jdhu@henau.edu.cn.
¹³ State Key Laboratory of Wheat and Maize Crop Science, Zhengzhou, 450002, China. jdhu@henau.edu.cn.

PMID: 38613710
DOI: 10.1007/s10895-024-03716-7

Abstract

Recent advances in detection and diagnostic tools have improved understanding and identification of plant physiological and biochemical processes. Effective and safe Surface Enhanced Raman Spectroscopy (SERS) can find objects quickly and accurately. Raman enhancement amplifies the signal by 10¹⁴-10¹⁵ to accurately quantify plant metabolites at the molecular level. This paper shows how to use functionalized perovskite substrates for SERS. These perovskite substrates have lots of surface area, intense Raman scattering, and high sensitivity and specificity. These properties eliminate sample matrix component interference. This study identified research gaps on perovskite substrates' effectiveness, precision, and efficiency in biological metabolite detection compared to conventional substrates. This article details the synthesis and use of functionalized perovskites for plant metabolites measurement. It analyzes their pros and cons in this context. The manuscript analyzes perovskite-based SERS substrates, including single-crystalline perovskites with enhanced optoelectronic properties. This manuscript aims to identify this study gap by comprehensively reviewing the literature and using it to investigate plant metabolite detection in future studies.

Keywords: Functionalized perovskites; Plant metabolite detection; Raman enhancement; SERS; Single-crystalline.

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