2-Ferrocenyl-2-[(2-ferrocenylethen-yl)(morpholin-4-yl)meth-yl]-1,3-di-thiol-ane

Claudia Oliva-Colunga; Jessica J Sánchez García; Marcos Flores-Alamo; Elena I Klimova

doi:10.1107/S2414314624002347

2-Ferrocenyl-2-[(2-ferrocenylethen-yl)(morpholin-4-yl)meth-yl]-1,3-di-thiol-ane

IUCrdata. 2024 Mar 21;9(Pt 3):x240234. doi: 10.1107/S2414314624002347. eCollection 2024 Mar.

Authors

Claudia Oliva-Colunga¹, Jessica J Sánchez García¹, Marcos Flores-Alamo¹, Elena I Klimova¹

Affiliation

¹ Facultad de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Ciudad de México, 04510, Mexico.

Abstract

The mol-ecular structure of 2-ferrocenyl-2-[(2-ferrocenylethen-yl)(morpholin-4-yl)meth-yl]-1,3-di-thiol-ane, [Fe₂(C₅H₅)₂(C₁₉H₂₁NOS₂)] or C₂₉H₃₁Fe₂NOS₂, has the ferrocenyl fragments in a trans disposition with respect to the vinyl group. One of the methyl-ene groups is disordered over two sites with occupancies of 0.782 (13):0.218 (13). In the crystal, cyclo-penta-dienyl-C-H⋯O(morpholin-yl) inter-actions feature within helical chains parallel to the c-axis direction. The chains are connected by methyl-ene- and cyclo-penta-dienyl-C-H⋯O(cyclo-penta-dien-yl) inter-actions.

Keywords: crystal structure; ferrocenyl; morpholine; stereochemistry.

Grants and funding

Funding for this research was provided by: Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México (grant No. IN 217421). The authors acknowledge CONAHCYT scholarship No. 479321 (CO-C).