Rice starch modification by thermal treatments with avocado oil: Autoclave versus microwave methods

Int J Biol Macromol. 2024 May;267(Pt 1):131426. doi: 10.1016/j.ijbiomac.2024.131426. Epub 2024 Apr 5.

Abstract

This study aimed to evaluate the physical and chemical alterations in rice starch modified by heat-moisture treatment (HMT) using an autoclave and a microwave, in association with avocado oil (AO), and evaluate the effects on thermal and structural properties, in vitro digestibility, and estimated glycemic index (eGI). Samples were adjusted to 30 % (w/w) moisture and 2, 4 and 8 % AO. HMT was conducted at 110 °C for 1 h in the autoclave (A0%, A2%, A4%, and A8%) and at 50 °C for 3 min in the microwave (M0%, M2%, M4%, and M8%). Both procedures did not alter the starch crystallinity pattern (type-A). Pasting viscosity, setback, relative crystallinity, and gelatinisation enthalpy decreased as the AO content increased in both HMT processes. The M8% showed reduced digestibility, decreased eGI (72.99, p < 0.05), and lower starch hydrolysis concentration (62.75 %, p < 0.05). The application of HMT with the addition of AO may be an interesting process for obtaining resistant starch since its content increased after both treatments (A8%, M4%, and M8%). The microwave process proved efficient, making it possible to use a lower temperature, less time, and less energy for modification and obtain starches with improved characteristics.

Keywords: Amylose-lipid complex; Digestibility; Estimated glycemic index; FTIR; Thermal properties.

MeSH terms

  • Hot Temperature*
  • Hydrolysis
  • Microwaves*
  • Oryza* / chemistry
  • Persea* / chemistry
  • Plant Oils* / chemistry
  • Starch* / chemistry
  • Viscosity

Substances

  • Starch
  • Plant Oils