Shaping sustainable pathways: Enhancing mechanical properties of biocomposite through tannic acid treatment of flax fabrics

Int J Biol Macromol. 2024 May;266(Pt 2):131393. doi: 10.1016/j.ijbiomac.2024.131393. Epub 2024 Apr 4.

Abstract

Biocomposites developed using natural fibers serve as a sustainable alternative to synthetic composite materials. However, narrowing the performance gap between synthetic composites and biocomposites requires serious efforts. A promising approach is the modification of natural fibers using various chemical treatments. This paper investigates the potential of tannic acid (TA) treatment as a sustainable approach to enhance mechanical performance and reduce moisture absorption of flax fabric-reinforced biocomposites. The methodology involves the treatment of flax woven fabric with tannic acid, a naturally occurring polyphenolic compound, followed by the fabrication of biocomposite using a green epoxy matrix. The variables studied during treatment are TA concentration and processing time. Characterization of untreated and treated flax fabric and its composites was done using various analytical techniques such as FTIR spectroscopy, moisture absorption and mechanical testing (tensile strength, flexural strength, and impact resistance). FTIR spectroscopy of TA-treated flax confirmed attachment of aromatic rings and carbon double bond formation, thus serving for properties enhancement. The mechanical characterization of composites showed that properties are enhanced up to an optimum limit of concentration and processing time i.e., 1 % concentration and 30 min of processing. Moisture absorption of the TA-treated composite also reduced significantly as compared to untreated composites. These findings contribute towards the advancement in sustainable biocomposites and pave the way for their utilization in various applications.

Keywords: Fiber modification; Flax fibers; Green epoxy; Mechanical characteristics; Tannic acid treatment.

MeSH terms

  • Biocompatible Materials / chemistry
  • Flax* / chemistry
  • Mechanical Phenomena
  • Polyphenols*
  • Spectroscopy, Fourier Transform Infrared
  • Tannins* / chemistry
  • Tensile Strength*
  • Textiles*

Substances

  • Tannins
  • Biocompatible Materials
  • Tannic Acid
  • Polyphenols