Managing PFAS exhausted Ion-exchange resins through effective regeneration/electrochemical process

Fatemeh Asadi Zeidabadi; Ehsan Banayan Esfahani; Sean T McBeath; Madjid Mohseni

doi:10.1016/j.watres.2024.121529

Managing PFAS exhausted Ion-exchange resins through effective regeneration/electrochemical process

Water Res. 2024 May 15:255:121529. doi: 10.1016/j.watres.2024.121529. Epub 2024 Mar 26.

Authors

Fatemeh Asadi Zeidabadi¹, Ehsan Banayan Esfahani¹, Sean T McBeath², Madjid Mohseni³

Affiliations

¹ Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada.
² Department of Civil and Environmental Engineering, University of Massachusetts Amherst, Amherst, MA 01003, United States.
³ Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada. Electronic address: madjid.mohseni@ubc.ca.

PMID: 38554630
DOI: 10.1016/j.watres.2024.121529

Abstract

This study proposes an integrated approach that combines ion-exchange (IX) and electrochemical technologies to tackle problems associated with PFAS contamination. Our investigation centers on evaluating the recovery and efficiency of IX/electrochemical systems in the presence of five different salts, spanning dosages from 0.1 % to 8 %. The outcomes reveal a slight superiority for NaCl within the regeneration system, with sulfate and bicarbonate also showing comparable efficacy. Notably, the introduction of chloride ion (Cl^-) into the electrochemical system results in substantial generation of undesirable chlorate (ClO₃^-) and perchlorate (ClO₄^-) by-products, accounting for ∼18 % and ∼81 % of the consumed Cl^-, respectively. Several agents, including H₂O₂, KI, and Na₂S₂O₃, exhibited effective mitigation of ClO₃^- and ClO₄^- formation. However, only H₂O₂ demonstrated a favorable influence on the degradation and defluorination of PFOA. The addition of 0.8 M H₂O₂ resulted in the near-complete removal of ClO₃^- and ClO₄^-, accompanied by 1.3 and 2.2-fold enhancements in the degradation and defluorination of PFOA, respectively. Furthermore, a comparative analysis of different salts in the electrochemical system reveals that Cl^- and OH^- ions exhibit slower performance, possibly due to competitive interactions with PFOA on the anode's reactive sites. In contrast, sulfate and bicarbonate salts consistently demonstrate robust decomposition efficiencies. Despite the notable enhancement in IX regeneration efficacy facilitated by the presence of methanol, particularly for PFAS-specific resins, this enhancement comes at the cost of reduced electrochemical decomposition of all PFAS. The average decay rate ratio of all PFAS in the presence of 50 % methanol, compared to its absence, falls within the range of 0.11-0.39. In conclusion, the use of 1 % Na₂SO₄ salt stands out as a favorable option for the integrated IX/electrochemical process. This choice not only eliminates the need to introduce an additional chemical (e.g., H₂O₂) into the wastewater stream, but also ensures both satisfactory regeneration recovery and efficiency in the decomposition process through electrochemical treatment.

Keywords: GenX; Hydrogen peroxide; Organic solvent; PFAS-specific resin; Perchlorate; Regeneration recovery.