Advances in the Applications of Clinoptilolite-Rich Tuffs

Materials (Basel). 2024 Mar 12;17(6):1306. doi: 10.3390/ma17061306.

Abstract

Adsorptive, catalytic, and antibacterial properties of clinoptilolite-rich tuffs (ZT) are presented here. ZT transformed into Fe-containing ZT (Fe-ZT) removes various organic and inorganic anions from water. Fe-ZT, which contains selenium, is beneficial for growing Pleurotus ostreatus mushrooms. The fungi convert inorganic Se from Fe-ZT into a more useful organically bonded form. ZT and Fe-ZT as supplements retain nitrogen and potassium in sandy, silty loam and silty clay soils. ZT shows an affinity toward toxic metal cations, which are essential for cleaning contaminated water. The adsorption of atenolol, acetylsalicylic, and salicylic acid onto M-ZT (M-Cu2+, Mn2+, Ni2+, or Zn2+) from water solutions suggests that both the natures of M and pharmaceuticals have a significant impact on the adsorption mechanism and determine the adsorption capability of the ZT. ZT is an excellent carrier for ultrafine (2-5 nm) nano oxide particles, which have been shown to have catalytic activity in different chemical processes and photodegradation reactions of organic pollutants. ZT can also be transformed into SO4-SnO2-ZT, which is catalytically active as a solid acid. M-ZT is an effective carrier of valuable bacteria. Ag-ZT possesses beneficial bactericidal activity in disinfecting water and soil remediation.

Keywords: adsorption; antimicrobial activity; biomass; catalysis; nano oxides; natural zeolite.

Publication types

  • Review

Grants and funding

This research was funded by the Ministry of Science, Technological Development and Innovation of the Republic of Serbia during the time of developing this review paper as an international collaborative project (Project number: 451-03-66/2024-03/200011) and the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement, MSCA-ITN-2018.