Anisotropic Local Structure of SrFe2- xNixAs2 (x = 0.00, 0.16, and 0.23) Superconductor Probed by Polarized X-ray Absorption Fine Structure Measurements

M Y Hacisalihoglu; L Tortora; G Tomassucci; L Simonelli; N L Saini

doi:10.3390/ma17061301

Anisotropic Local Structure of SrFe_{2- x}Ni_xAs₂ (x = 0.00, 0.16, and 0.23) Superconductor Probed by Polarized X-ray Absorption Fine Structure Measurements

Materials (Basel). 2024 Mar 11;17(6):1301. doi: 10.3390/ma17061301.

Authors

M Y Hacisalihoglu^{1

2}, L Tortora¹, G Tomassucci¹, L Simonelli³, N L Saini¹

Affiliations

¹ Department of Physics, Sapienza University of Rome, P. le Aldo Moro 2, 00185 Rome, Italy.
² Department of Physics, Recep Tayyip Erdogan University, Rize 53100, Turkey.
³ CELLS-ALBA Synchrotron Radiation Facility, Carrer de la Llum 2-26, Cerdanyola del Valles, 08290 Barcelona, Spain.

Abstract

We have investigated the effect of the Ni substitution on the local structure and the valence electronic states of the SrFe2-xNixAs2 (x = 0.00, 0.16, and 0.23) superconductor with a multi-edge extended X-ray absorption fine structure (EXAFS) and X-ray absorption near edge structure (XANES) spectroscopy. The As K-edge and Fe K-edge EXAFS measurements in the two polarizations (E‖ab and E‖c) show a clear change in the local structure with Ni concentration. The near-neighbor bondlengths and the related mean-square relative displacements (MSRDs) decrease as the Ni content increases. The polarized XANES spectra at the As, Fe and Ni K edges reveal a systematic change in the anisotropy of the valence electronic structure. The results suggest that the quasi 2D electronic structure of this system tends to become more isotropic as the Ni content increases. The local structure and the valence electronic states are discussed in the frame of the evolving electronic transport of the SrFe2-xNixAs2 system.

Keywords: X-ray absorption spectroscopy; iron-based superconductors; local structure.

Grants and funding

One of us (M.Y.H.) would also like to acknowledge Sapienza University for the support to work in Italy.