Simultaneous immobilization of V and Cr availability, speciation in contaminated soil and accumulation in ryegrass by using Fe-modified pyrolysis char

Abstract

In this study, municipal waste pyrolytic char (PEWC) was prepared by pyrolysis from municipal solid waste extracted in landfills, and Fe-based modified pyrolytic char (Fe-PEWC) was prepared by modification. Focusing on the evaluation of the stabilization capacity of Fe-PEWC for vanadium (V) and chromium (Cr) in soils, the effects of PEWC addition on soil properties, bioavailability and morphological distribution of V and Cr, ryegrass growth, and V and Cr accumulation were thoroughly investigated. The results of pot experiment showed that the application of PEWC and Fe-PEWC significantly (P < 0.05) improved soil properties (such as pH, EC, total nitrogen, available phosphorus, available potassium, and organic matter). After 42 days of cultivation, Fe-PEWC has a better fixation effect on heavy metals, and the bioavailable V and Cr of 3% Fe-PEWC decreased by 14.96% and 19.48%, respectively. The exchangeable state and reducible state decreased, while the oxidizable state and residual state increased to varying degrees. The Fe-PEWC can effectively reduce the accumulation of V and Cr in ryegrass by 71.25% and 76.43%, respectively, thereby reducing their toxicity to plants. In summary, modified pyrolytic char can effectively solidify heavy metals in soil, improve soil ecology and reduce the toxicity to plants. The use of excavated waste as a raw material for the preparation of soil heavy metal curing agent has the significance of resource recycling, low price, and practical application.

Keywords: Cr-contaminate soil; Immobilization; Municipal solid waste; Pyrolysis char; V-contaminate soil.