Immobilization of rare-earth doped aluminate nanoparticles encapsulated with silica into polylactic acid-based color-tunable smart plastic window

Abstract

An inorganic/organic nanocomposite was used to develop an afterglow and color-tunable smart window. A combination of polylactic acid (PLA) plastic waste as an environmentally-friendly hosting agent, and lanthanide-activated strontium aluminum oxide nanoparticles (SAON) encapsulated with silica nanoparticles (SAON@Silica) as a photoluminescent efficient agent resulted in a smart organic/inorganic nanocomposite. In order to prepare SAON-encapsulated silica nanoparticles (SAON@Silica), the SAON nanoparticles were coated with silica using the heterogeneous precipitation method. By using transmission electron microscopy (TEM), SAON showed a diameter range of 5-12 nm, while the SAON@Silica nanoparticles showed a diameter range of 50-100 nm. In order to ensure the development of a colorless plastic film, a homogeneous dispersion of the phosphorescent Phosphor@Silica nanoparticles throughout the plastic bulk was confirmed. CIE Lab coordinates and luminescence spectra were used to study the color shift characteristics. Under visible light conditions, the plastic films were transparent. The photoluminescent films emitted green light at 525 nm when excited at 375 nm. The hydrophobicity and ultraviolet protection were enhanced without altering the fundamental physico-mechanical performance of the plastic sheet. The current color-tunable plastic can be used in many potential applications, such as warning signs, anti-counterfeiting barcodes, smart windows, and protective apparel.

Keywords: Photoluminescent smart polylactic acid window; Rare-earth doped aluminate; Silicon dioxide.