Self-propelled object that generates a boundary with amphiphiles at an air/aqueous interface

Abstract

A benzoic acid (BA) disk was investigated as a novel self-propelled object whose driving force was the difference in surface tension. 4-Stearoyl amidobenzoic acid (SABA) was synthesized as an amphiphile to control the nature of motion based on intermolecular interactions between BA and SABA. The BA disk exhibited characteristic motion depending on the surface density of the SABA on the aqueous phase, that is, reciprocating motion as a one-dimensional motion and restricted and unrestricted motion as a two-dimensional motion. The trajectory of the reciprocating motion was determined by the initial direction of motion, and the boundary between an aqueous surface and the BA-SABA condensed molecular layer was used as the field's boundary. The presented results indicate that the characteristic nature of motion can be designed at the molecular level based on the intermolecular interactions between an energy-source molecule and an amphiphile.

Keywords: Amphiphiles; Benzoic acid; Intermolecular interaction; Reciprocating motion; Self-propulsion.