The global freshwater crisis is a pressing issue, especially in areas with little rainfall and inner continental regions. The growing attention to water scarcity has induced increased interest in research on advanced water treatment technologies. As an abundant bioactive material in nature, sodium alginate (SA) has been widely used in water management due to its outstanding water absorption and holding ability, reversible swelling property, and pollutant adsorption performance. Building on this, progress made in using various modified forms of SA to access clean water is addressed in this review. Covering studies concern the adsorption and separation of pollutants in wastewater by SA-based absorbents and freshwater harvesting by SA-based collectors. This review explores SA-based composites' composition-structure-construction designs and emphasizes the impact of materials like inorganic materials, functional polymers, and porous matrices and how they can be exploited for water treatment. It also highlights the mechanisms of contaminants adsorption and freshwater desorption of SA-based composites. Finally, the shortcomings and future orientation of SA-based composites are proposed, including performance optimization, structural modification, application expansion, and mechanism in-depth investigation. This review aims to offer a theoretical basis and technical guidance for the use of natural materials to respond to the shortage of freshwater resources.
Keywords: Adsorption mechanism; Atmospheric water harvesting; Desalination; Water purification.
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