The antibiotic oxytetracycline (OCA) exhibits high insolubility in the natural environment, posing a significant challenge for its removal. This study synthesized a porous structure and a high-surface-area carbon fiber, incorporating zinc oxide (ZnO/CFB) for the effective removal of OCA in wastewater. The material characterization revealed exceptional optical and photochemical properties of ZnO/CFB, featuring a reduced band gap energy of 2.7 eV. ZnO/CFB exhibited robust performance in the photodegradation of OCA in wastewater, achieving an impressive removal efficiency of 86.7%. Remarkably, the reduction of total organic carbon (TOC) reached an outstanding 97.5%. LC-MS analysis confirmed the complete oxidation of OCA and its intermediates, transforming them into inorganic substances within 60 min. This study introduces an efficient strategy for eliminating antibiotic pollutants from wastewater, highlighting the potential of ZnO/CFB as an effective and stable photocatalyst for environmental remediation.
Keywords: Antibiotic pollutants; ZnO-based photocatalyst; oxytetracycline antibiotic; wastewater.