Characterization of PPS Piston and Packing Ring Materials for High-Pressure Hydrogen Applications

Polymers (Basel). 2024 Feb 1;16(3):412. doi: 10.3390/polym16030412.

Abstract

The widespread adoption of renewable energy hinges on the efficient transportation of hydrogen. Reciprocating piston compressor technology in non-lubricated operation will play a key role, ensuring high flow rates and compression ratios. These systems rely on advanced high-strength sealing solutions for piston and rod packing rings utilizing advanced fiber-reinforced polymers. Polyphenylene sulfide (PPS) polymer matrix composites have seen use in tribological applications and promise high mechanical strength and wear resistance. The presented work describes carbon and glass fiber-reinforced PPS matrix polymers in comparison, which are characterized by complementary methods to investigate their properties and potential for application in reciprocating compressor under non-lubricated operation. Thermo-mechanical and tribological testing was supported by microstructure analysis utilizing advanced X-ray and electron imaging techniques. New insights in micromechanical deformation behavior in regard to fiber materials, interface strength and orientation in fiber-reinforced polymers are given. Conclusions on the suitability of different PPS matrix composites for high-pressure hydrogen compression applications were obtained.

Keywords: X-ray imaging; fiber-reinforced polymers; friction and wear; hydrogen technology; thermo-mechanical properties; transmission electron microscopy; visco-elastic deformation.

Grants and funding

The detailed CT-Data evaluations were supported by the project “Hydrogen Based Research Infrastructure Development” (HyBRID) funded by the federal government of Upper Austria and the Just Transition Fund (JTF) in the framework of the EU-Program “IBW-EFRE/JTF 2021-2027”. Parts of the research results presented were provided in cooperation with AC2T research GmbH and funded by the Austrian COMET program (Project: COMET K2 InTribology, No. 872176; Project Management Organization: AC2T research GmbH, Center of Excellence for Tribology).