Highly-exposed copper and ZIF-8 interface enables synthesis of hydrocarbons by electrocatalytic reduction of CO2

Abstract

Electrochemical reduction of CO₂ (CO₂RR) to fuels and chemicals is a promising route to close the anthropogenic carbon cycle for sustainable society. The Cu-based catalysts in producing high-value hydrocarbons feature unique superiorities, yet challenges remain in achieving high selectivity. In this work, Cu@ZIF-8 NWs with highly-exposed Cu nanowires (Cu NWs) and ZIF-8 interface are synthesized via a surfactant-assisted method. Impressively, Cu@ZIF-8 NWs exhibit excellent stability and a high Faradaic efficiency of 57.5% toward hydrocarbons (CH₄ and C₂H₄) at a potential of -0.7 V versus reversible hydrogen electrode. Computational calculations combining with experiments reveal the formation of Cu and ZIF-8 interface optimizes the adsorption of reaction intermediates, particularly stabilizing the formation of *CHO, thereby enabling efficient preference for hydrocarbons. This work highlights the potential of constructing metals and MOFs heterogeneous interfaces to enhance catalytic properties and offers valuable insights for the design of highly efficient CO₂RR catalysts.

Keywords: CO(2) reduction; Cu-based electrocatalysts; Energy conversion; Heterostructures; Hydrocarbons; Metal-organic frameworks.