Recovery of isolated lithium through discharged state calendar ageing

Wenbo Zhang; Philaphon Sayavong; Xin Xiao; Solomon T Oyakhire; Sanzeeda Baig Shuchi; Rafael A Vilá; David T Boyle; Sang Cheol Kim; Mun Sek Kim; Sarah E Holmes; Yusheng Ye; Donglin Li; Stacey F Bent; Yi Cui

doi:10.1038/s41586-023-06992-8

Recovery of isolated lithium through discharged state calendar ageing

Nature. 2024 Feb;626(7998):306-312. doi: 10.1038/s41586-023-06992-8. Epub 2024 Feb 7.

Authors

Affiliations

¹ Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA.
² Department of Chemistry, Stanford University, Stanford, CA, USA.
³ Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
⁴ Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA. yicui@stanford.edu.
⁵ Stanford Institute for Materials Energy and Energy Sciences, SLAC National Laboratory, Menlo Park, CA, USA. yicui@stanford.edu.

^# Contributed equally.

PMID: 38326593
DOI: 10.1038/s41586-023-06992-8

Abstract

Rechargeable Li-metal batteries have the potential to more than double the specific energy of the state-of-the-art rechargeable Li-ion batteries, making Li-metal batteries a prime candidate for next-generation high-energy battery technology^1-3. However, current Li-metal batteries suffer from fast cycle degradation compared with their Li-ion battery counterparts^2,3, preventing their practical adoption. A main contributor to capacity degradation is the disconnection of Li from the electrochemical circuit, forming isolated Li^4-8. Calendar ageing studies have shown that resting in the charged state promotes further reaction of active Li with the surrounding electrolyte^9-12. Here we discover that calendar ageing in the discharged state improves capacity retention through isolated Li recovery, which is in contrast with the well-known phenomenon of capacity degradation observed during the charged state calendar ageing. Inactive capacity recovery is verified through observation of Coulombic efficiency greater than 100% on both Li||Cu half-cells and anode-free cells using a hybrid continuous-resting cycling protocol and with titration gas chromatography. An operando optical setup further confirms excess isolated Li reactivation as the predominant contributor to the increased capacity recovery. These insights into a previously unknown pathway for capacity recovery through discharged state resting emphasize the marked impact of cycling strategies on Li-metal battery performance.