Red mud-based perovskite oxygen carrier preparation for chemical looping gasification of municipal sludge

Abstract

Chemical looping gasification (CLG) is a promising technology that utilizes lattice oxygen for partial oxidation of solid organic waste to produce high-quality syngas. The utilization of low-cost and high-performance oxygen carriers (OCs) is important for the success of this technology. The red mud from aluminum production was mixed with calcium and manganese oxides to prepare CaMn_0.5Fe_0.5O_3-δ perovskite OCs. The comparative redox tests were carried out to analyze the reactivity using a thermogravimetric analyzer (TGA). Multiple cycle CLG experiments were conducted on a wet municipal sludge in a lab-scale fluidized bed to produce the hydrogen-rich gas. The results showed that the CaMn_0.5Fe_0.5O_3-δ-washed demonstrated higher oxygen transfer capacity and better cycling stability with a maximum weight loss of 7.3096 %. After the 5th cycle in CLG, the syngas obtained using CaMn_0.5Fe_0.5O_3-δ-washed maintained a H₂ volume fraction exceeding 40%. However, an increase in CO₂ production was also observed, which could be due to the catalytic effect of MnO in the OC on the steam-reforming reaction. The XRD curves showed that fresh CaMn_0.5Fe_0.5O_3-δ-washed exhibited prominent diffraction peaks characteristic of perovskite. It was observed that after undergoing 5 cycles, the presence of iron calcium silicate structures containing Mn became evident due to the attachment of sludge ash, leading to the increased impurities on the surface of OCs with a decrease in the specific surface area. Additionally, some of the reacted OC particles exhibited a hollow structure, facilitating the fluidization. This preliminary study provides the basis for the improvement of the OC performance in sludge gasification.

Keywords: Chemical looping gasification; Hydrogen-rich gas; Municipal sludge; Perovskite oxygen carrier; Red mud.