Determination of the most significant rubber components influencing the hardness of natural rubber (NR) using various statistical methods

Heliyon. 2024 Jan 24;10(3):e25170. doi: 10.1016/j.heliyon.2024.e25170. eCollection 2024 Feb 15.

Abstract

Manufacturers use a large number of components in the production of modern rubber products. The selection of the constituents of the rubber recipe is primarily determined by the purpose of use. The different fields of applications of rubbers require the presence of appropriate mechanical properties. In this respect, it can be useful to know which substances forming the rubber recipe have significant influence on the different mechanical properties. In this study, the statistical analysis of the influence of rubber components on the hardness of natural rubber (NR) is proposed based on literature review. Based on the literature data, various statistical analyses, like linear regression, constrained linear regression, Ridge regression, Ridge sparse regression and binary classification decision trees were performed to determine which rubber components have the most significant effect on the hardness. In the statistical analyses, the effect of a total of 42 constituents of rubber compound on hardness was investigated. Most of the applied statistical methods confirmed that the traditional frequently used rubber components, such as carbon black and sulfur, have a primary effect on the hardness. However, the substances forming the rubber compound that are not widely used in practice or newly developed components appear differently in the lists of significant additives obtained by the different statistical methods.

Keywords: Binary decision tree; Linear regression; Natural rubber; Ridge regression; Shore a hardness; statistical analysis; t-test.