Bis(2-hy-droxy-2,3-di-hydro-1 H-inden-1-aminium) tetra-chlorido-palladate(II) hemihydrate

Ovender Singh; Jungwi Mok; Hyoung-Ryun Park; Junseong Lee

doi:10.1107/S2414314624000592

Bis(2-hy-droxy-2,3-di-hydro-1 H-inden-1-aminium) tetra-chlorido-palladate(II) hemihydrate

IUCrdata. 2024 Jan 26;9(Pt 1):x240059. doi: 10.1107/S2414314624000592. eCollection 2024 Jan.

Authors

Ovender Singh¹, Jungwi Mok¹, Hyoung-Ryun Park¹, Junseong Lee¹

Affiliation

¹ Department of Chemistry, Chonnam National University, Gwangju, Republic of Korea.

Abstract

A new square-planar palladium complex salt hydrate, (C₉H₁₂NO)₂[PdCl₄]·0.5H₂O, has been characterized. The asymmetric unit of the complex salt comprises two [PdCl₄]^2- dianions, four 2-hy-droxy-2,3-di-hydro-1H-inden-1-aminium cations, each derived from (1R,2S)-(+)-1-amino-indan-2-ol, and one water mol-ecule of crystallization. In the crystal, a two-dimensional layer parallel to (001) features a number of O-H⋯O, N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds.

Keywords: aminoindanol; crystal structure; hydrogen bonding; palladium tetrachloride.

Grants and funding

Funding for this research was provided by: National Research Foundation of Korea (grant No. 2022R1A2C100611312).