trans-Di-chlorido-bis-[(S)-(-)-1-(4-methyl-phen-yl)ethyl-amine-κ N]palladium(II)

Guadalupe Hernández Téllez; Gloria E Moreno Morales; Pankaj Sharma; Rodary Gonzalez; Bertin Anzaldo

doi:10.1107/S2414314624000361

trans-Di-chlorido-bis-[(S)-(-)-1-(4-methyl-phen-yl)ethyl-amine-κ N]palladium(II)

IUCrdata. 2024 Jan 12;9(Pt 1):x240036. doi: 10.1107/S2414314624000361. eCollection 2024 Jan.

Authors

Guadalupe Hernández Téllez¹, Gloria E Moreno Morales¹, Pankaj Sharma², Rodary Gonzalez², Bertin Anzaldo¹

Affiliations

¹ Lab. Síntesis de Complejos, Fac. Cs. Quím.-BUAP, Ciudad Universitaria, PO Box 72592 Puebla, Mexico.
² Instituto de Química Universidad Autónoma de México UNAM, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, Mexico.

Abstract

The title complex, [PdCl₂(C₉H₁₃N)₂], comprises a single mol-ecule in the asymmetric unit. The Pd^II atom is tetra-coordinated by two N atoms from two trans-aligned organic ligands and two Cl ligands, forming a square-planar metal coordination environment. The distances from the ortho-H atoms on the phenyl ring to the central Pd^II atom fall within the range 4.70-5.30 Å, precluding any significant intra-molecular Pd⋯H inter-actions.

Keywords: amine; crystal structure; monodentate ligand; palladium(II) complex.