Effect of Temperature and Alkali Solution to Activate Diethyl Carbonate for Improving Rheological Properties of Modified Hydroxyethyl Methyl Cellulose

Ghulam Abbas; Abdul Haque Tunio; Khalil Rehman Memon; Aftab Ahmed Mahesar; Faisal Hussain Memon

doi:10.1021/acsomega.3c07451

Effect of Temperature and Alkali Solution to Activate Diethyl Carbonate for Improving Rheological Properties of Modified Hydroxyethyl Methyl Cellulose

ACS Omega. 2024 Jan 18;9(4):4540-4554. doi: 10.1021/acsomega.3c07451. eCollection 2024 Jan 30.

Authors

Ghulam Abbas¹, Abdul Haque Tunio¹, Khalil Rehman Memon¹, Aftab Ahmed Mahesar¹, Faisal Hussain Memon²

Affiliations

¹ Institute of Petroleum & Natural Gas Engineering, Mehran University of Engineering & Technology, Jamshoro 76062, Sindh, Pakistan.
² Department of Petroleum & Natural Gas Engineering, Mehran University of Engineering and Technology, S.Z.A.B Campus, Khairpur Mir's 66020, Sindh, Pakistan.

Abstract

The applications of cellulose ethers in the petroleum industry represent various limitations in maintaining their rheological properties with an increase in both concentration and temperature. This paper proposed a new method to improve the rheological properties of hydroxyethyl methyl cellulose (HEMC) by incorporating diethyl carbonate (DEC) as a transesterification agent and alkali base solutions. Fourier transform infrared (FTIR) analysis confirmed the grafting of both composites onto the HEMC surface. The addition of sodium hydroxide (NaOH) improved the stability of the polymeric solution as observed from ζ-potential measurement. Shear viscosity and frequency sweep experiments were conducted at concentrations of 0.25-1 wt % at ambient and elevated temperatures ranging from 80-110 °C using a rheometer. In the results, the increase in viscosity at specific times and temperatures indicated the activation of DEC through the saponification reactions with alkali solutions. All polymeric solutions exhibited shear-thinning behavior and were fitted well by the Cross model. NaOH-based modified solution exhibited low shear viscosity compared to the DEC-HEMC solution at ambient temperature. However, at 110 °C, its viscosity exceeded that of the DEC-HEMC solution due to the activation of DEC. In frequency sweep analysis, the loss modulus (G″) was greater than the storage modulus (G') at lower frequencies and vice versa at higher frequencies. This signifies the viscoelastic behavior of modified solutions at 0.50 wt % and higher concentrations. The flow point (G' = G″) shifted to a low frequency, indicating the increasing dominance of elastic behavior with the rising temperature. At 110 °C, the NaOH-based modified solution exhibited both viscous and elastic behavior, confirming the solution's thermal stability and flowability. In conclusion, modified HEMC solution was found to be effective in controlling viscosity under ambient conditions, enhancing solubility, and improving thermal stability. This modified composite could play a significant role in optimizing viscoelastic properties and fluid performance under challenging wellbore conditions.