Green in situ synthesis of sandwich-like W-bridged siligraphene (g-SiC@WC@g-SiC) heterostructure from Saccharum Ravennae gum for ultrahigh-rate photodegradation of acetaminophen

Abstract

Herein, the sandwich-like W-bridged siligraphene (W/g-SiC) as a heterojunction of WC and siligraphene nanosheets have been first accomplished via a simple green synthesis using Saccharum Ravennae gum as a natural Si and W sources and gelatin as a natural C and N sources. In a magnesiothermic process, Si and C atoms bond together and form a graphene-like structure where half of the C atoms are replaced by Si atoms. The presence of W in the natural precursor creates a W-doped siligraphene structure. Tungsten in the form of carbide (WC) creates a heterojunction with g-SiC, which reduces the bandgap. According to the experimental and computational data, the proposed structure of W/g-SiC was predicted by replacing the W atoms with Si atoms and bonding with C atoms in the siligraphene structure. The W-C bond in this structure is elongated and the W atom comes out of the siligraphene sheet and is placed between two siligraphene layers to interact with three carbons from the next layer. Under visible light irradiation, holes are generated on the g-SiC layers and electrons in the WC interlayer, which makes it a highly efficient photocatalyst with ultrafast charge separation and active surface for the removal of Acetaminophen.

Keywords: Acetaminophen; Photocatalyst; Siligraphene; Tungsten carbide; W-bridged.