Evaluation of fuel properties for possible biodiesel output based on the fatty acid composition of oleaginous plants and microalgae

Sci Total Environ. 2024 Mar 25:918:170448. doi: 10.1016/j.scitotenv.2024.170448. Epub 2024 Jan 30.

Abstract

In the past decade, there has been a significant rise in sustainable biomass based biofuel production to address energy needs while mitigating environmental impacts. Traditionally, bioethanol was used for biofuel production, but concerns over food security and environmental preservation have led to growing interest in alternative sources such as neutral lipids from vegetable oil and microalgae for biodiesel production. This research paper evaluates the potential of various oleaginous plants and microalgae as feedstocks for biodiesel production, with a focus on their fatty acid composition and its impact on biodiesel properties. The study examines the fatty acid profiles of 43 different plant and microalgae species and employs various equations to estimate key physical properties of biodiesel. Additionally, the communication compares these properties to International Biodiesel Standards (EN 14214 and ASTM D6751-08) to assess the suitability of the derived biodiesel for commercial use. It is impossible to describe a single composition that is optimal in terms of all essential fuel properties due to the opposing effects of some structural features of the Fatty Acid Methyl Esters (FAME). However, biodiesel should contain relatively low concentrations of both long chain saturated and polyunsaturated FAME to ensure adequate efficiency in terms of low temperature operability and oxidative stability. The results reveal significant variations in properties amongst different feedstocks, highlighting the importance of feedstock selection in biodiesel production. The study also establishes correlations between various fuel properties, providing valuable insights in to optimizing biodiesel production processes, which will be of great use to researchers, engineers, and stakeholders involved in biodiesel production.

Keywords: Biodiesel; FAMEs profile; Fuel properties; Microalgae; Vegetable oils.

MeSH terms

  • Biofuels
  • Biomass
  • Cold Temperature
  • Fatty Acids* / chemistry
  • Microalgae*
  • Plant Oils / chemistry

Substances

  • Fatty Acids
  • Biofuels
  • Plant Oils