Progress in Anode Stability Improvement for Seawater Electrolysis to Produce Hydrogen

Adv Mater. 2024 Jan 25:e2311322. doi: 10.1002/adma.202311322. Online ahead of print.

Abstract

Seawater electrolysis for hydrogen production is a sustainable and economical approach that can mitigate the energy crisis and global warming issues. Although various catalysts/electrodes with excellent activities have been developed for high-efficiency seawater electrolysis, their unsatisfactory durability, especially for anodes, severely impedes their industrial applications. In this review, attention is paid to the factors that affect the stability of anodes and the corresponding strategies for designing catalytic materials to prolong the anode's lifetime. In addition, two important aspects-electrolyte optimization and electrolyzer design-with respect to anode stability improvement are summarized. Furthermore, several methods for rapid stability assessment are proposed for the fast screening of both highly active and stable catalysts/electrodes. Finally, perspectives on future investigations aimed at improving the stability of seawater electrolysis systems are outlined.

Keywords: anodes, corrosion; electrochemical H2 production; seawater electrolysis; selectivity; stability.

Publication types

  • Review